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KMID : 0370220090530030161
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Yakhak Hoeji
2009 Volume.53 No. 3 p.161 ~ p.164
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Studies Directed Toward Asymmetric Total Synthesis of Calycotomine
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Yang Jung-Eun
Jung Jae-Kyung
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Abstract
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Synthetic studies directed toward an asymmetric total synthesis of calycotomine, an representative tetrahydroisoquinoline, are described. The application of N-tert-butane sulfinyl chiral auxiliary to the Pictet-Spengler type reaction for the efficient synthesis of tetrahydroisoquinoline skeleton has been also investigated.
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KEYWORD
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tetrahydroisoquinoline, Pictet-Spengler reaction, alkaloid, N-tert-butane sulfinyl, calycotomine
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